Cu2O/CuS/ZnS Nanocomposite Boosts Blue LED-Light-Driven Photocatalytic Hydrogen Evolution
نویسندگان
چکیده
In the present work, we described synthesis and characterization of ternary Cu2O/CuS/ZnS nanocomposite using a facile two-step wet chemical method for blue LED-light-induced photocatalytic hydrogen production. The concentrations ZnS precursor reaction time were essential in controlling production efficiency under LED light irradiation. optimized exhibited maximum evolution rate 1109 µmolh−1g−1, which was remarkably higher than Cu2O nanostructures. Through cycle stability it can be observed that decreased after 4 cycles (1 = 3 h), but remained at 82.2% initial performance These reasons are mainly attributed to introduction CuS construct rationally coupled system, enables synergistic utilization photogenerated carriers increased absorption visible boosting LED-light-driven evolution.
منابع مشابه
Solar light-driven photocatalytic hydrogen evolution over ZnIn2S4 loaded with transition-metal sulfides
A series of Pt-loaded MS/ZnIn2S4 (MS = transition-metal sulfide: Ag2S, SnS, CoS, CuS, NiS, and MnS) photocatalysts was investigated to show various photocatalytic activities depending on different transition-metal sulfides. Thereinto, CoS, NiS, or MnS-loading lowered down the photocatalytic activity of ZnIn2S4, while Ag2S, SnS, or CuS loading enhanced the photocatalytic activity. After loading ...
متن کاملRed-light-driven photocatalytic hydrogen evolution using a ruthenium quaterpyridine complex.
A high-temperature, microwave synthesis of [Ru(qpy)3](2+) (qpy = 4,4':2',2'':4'',4'''-quaterpyridine) affords the photosensitiser in quantitative yield. The complex produces H2 photocatalytically in a range extending from the UV region of the spectrum to the red with greater efficiency when compared to [Ru(bpy)3](2+).
متن کاملCdS-graphene Nanocomposite for Efficient Visible-light-driven Photocatalytic and Photoelectrochemical Applications.
This paper reports cadmium sulphide nanoparticles-(CdS NPs)-graphene nanocomposite (CdS-Graphene), prepared by a simple method, in which CdS NPs were anchored/decorated successfully onto graphene sheets. The as-synthesized nanocomposite was characterized using standard characterization techniques. A combination of CdS NPs with the optimal amount of two-dimensional graphene sheets had a profound...
متن کاملA triad [FeFe] hydrogenase system for light-driven hydrogen evolution.
A novel molecular triad [FeFe]-H(2)ase 1, and its model complexes 2 and 3 have been successfully constructed. The multistep PET and long-lived Fe(i)Fe(0) species were found to be responsible for the better performance of triad 1 than that of 2 with 3 for light-driven H(2) evolution.
متن کاملTriazine-based carbon nitrides for visible-light-driven hydrogen evolution.
A new dimension: The doping of amorphous poly(triazine imide) (PTI) through ionothermal copolymerization of dicyandiamide with 4-amino-2,6-dihydroxypyrimidine (4AP) results in triazine-based carbon nitrides with increased photoactivity for water splitting compared to crystalline poly(triazine imide) (PTI/Li(+)Cl(-), see picture) and melon-type carbon nitrides. This family of carbon nitride semi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Catalysts
سال: 2022
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal12091035